Feyenoord are equal favourites for the title after edging out MTN FA Cup holders, Medeama to complete the pairings for the semi-final round.
The second-tier side, Inter Allies, King Faisal and Asante Kotoko won their respective quarterfinals matches to advance to the last four.
And Feyenoord, the only Division One League side still in the competition host Inter Allies on Sunday at the Accra Stadium in the first semi-final clash.
The derby in Kumasi on 17 May 2014 will see Kotoko and King Faisal battle for a place in the finals.
Semi-final pairings
11 May 2014
Feyenoord vs Inter Allies - Accra Stadium
17 May 2014
Asante Kotoko vs King Faisal - Baba Yara Stadium